In the article “Light-Induced Ferroelectric Modulation of p-n Homojunctions in Monolayer MoS2” by Mariola O Ramirez, Jaime Fernandez-Tejedor, Daniel Gallego, Javier Fernández-Martinez, Pablo Molina, David Hernández-Pinilla, Julio Gómez-Herrero, Pablo Ares and Luisa E. Bausá, the combined effect of
#ferroelectricity and light on the
#optoelectronicproperties of monolayer (1L)-MoS2 deposited on periodically poled
#lithiumniobate crystals is explored. *
Using scanning micro-photoluminescence, the effect of excitation intensity, scanning direction, and
#domainwalls on the 1L-MoS2
#photoluminescence properties is analyzed, offering insights into charge modulation of
#MoS2. *
The findings unveil a photoinduced charging process dependent on the
#ferroelectricdomainorientation, in which light induces charge generation and transfer at the monolayer-substrate interface. *
This highlights the substantial role of light excitation in ferroelectrically-driven electrostatic doping in MoS2.
Additionally, the work provides insights into the effect of the strong, nanometrically confined electric fields on LiNbO3 domain wall surfaces, demonstrating precise control over charge carriers in MoS2, and enabling the creation of deterministic p-n homojunctions with exceptional precision.
The results suggest prospects for novel optoelectronic and photonic application involving monolayer TMDs by combining light-matter interaction processes and the surface selectivity provided by ferroelectric domain structures.
To corroborate the optical results, Mariola O Ramirez et al. measured current-voltage (I-V) curves by using two
#AFMcantilevers with platinum-coated
#AFMtips in contact with the 1L-MoS2 i) on a single domain region, and ii) on both sides of a ferroelectric domain wall where the p-n junction is formed. The results are shown in Figure 3c. (cited in here).
The
#electricalcharacterization was carried out by means of a home-built two-terminal probe station with 2 sets of xyz piezomotors that allow precise positioning of the electrical probes.
NANOSENSORS™ AdvancedTEC™ ATEC-EFM
#tipviewAFMprobes, conductive AFM tips that protrude from the very end of the AFM cantilever, ensuring real AFM tip visibility from above for a soft and accurate mechanical and electrical contact. *