How PLLA Spherulites Fragment or Disintegrate Under Deformation: Insights from AFMWed Nov 04 2026
What happens to the crystalline structures inside a semicrystalline polymer when the material is stretched? A study by Xabier Larrañaga and colleagues, published in Macromolecules, reveals two contrasting deformation pathways in poly(L-lactic acid) (PLLA): fragmentation, in which crystalline order is locally retained, and mechanical disintegration, in which the structure becomes substantially less ordered. Atomic force microscopy (AFM), combined with Raman spectroscopy and polarized-light microscopy, helps explain these different responses.
Physical aging and the deformation of PLLA



